Synthesis of the (N2)3− Radical from Y2+ and Its Protonolysis Reactivity To Form (N2H2)2− via the Y[N(SiMe3)2]3/KC8 Reduction System
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja1116827
Reference55 articles.
1. Isolation of Dysprosium and Yttrium Complexes of a Three-Electron Reduction Product in the Activation of Dinitrogen, the (N2)3− Radical
2. Reduction of Dinitrogen to Planar Bimetallic M2(μ-η2:η2-N2) Complexes of Y, Ho, Tm, and Lu Using the K/Ln[N(SiMe3)2]3 Reduction System
3. Expanding Dinitrogen Reduction Chemistry to Trivalent Lanthanides via the LnZ3/Alkali Metal Reduction System: Evaluation of the Generality of Forming Ln2(μ-η2:η2-N2) Complexes via LnZ3/K
4. Expanding the LnZ3/Alkali-Metal Reduction System to Organometallic and Heteroleptic Precursors: Formation of Dinitrogen Derivatives of Lanthanum
5. The Elusive (C5Me4H)3Lu: Its Synthesis and LnZ3/K/N2 Reactivity
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