Synthesis and Bonding in the Diamagnetic Dinuclear Tantalum(IV) Hydride Species ([P2N2]Ta)2(μ-H)4 and the Paramagnetic Cationic Dinuclear Hydride Species {([P2N2]Ta)2(μ-H)4}+I- ([P2N2] = PhP(CH2SiMe2NSiMe2CH2)2PPh): The Reducing Ability of a Metal−Metal Bond
Author:
Affiliation:
1. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om000359w
Reference49 articles.
1. Stepwise Reduction of Dinitrogen to Nitride Assisted by Niobium Bonded to Oxygen Donor Atoms: The Potential of Reduced Forms of Niobium Calix[4]arene
2. Synthetic Analogs for the MoFe3S3 Subunit of the Nitrogenase Cofactor: Structural Features Associated with the Total Number of Valence Electrons and the Possible Role of M−M and Multiple M−S Bonding in the Function of Nitrogenase
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