Redefining the Coordination Geometry and Reactivity of Guanidinate Complexes by Covalently Linking the Guanidinate Ligands. Synthesis and Reactivity of [RN{NH(R)}CN(CH2)2NC{NH(R)}NR]M(CH2Ph)2 (R = iPr; M = Ti, Zr)
Author:
Affiliation:
1. Department of Chemistry and the Center for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario, Canada K1N 6N5
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om020830g
Reference25 articles.
1. The coordination chemistry of guanidines and guanidinates
2. Tetrasubstituted Guanidinate Anions as Supporting Ligands in Organoyttrium Chemistry
3. Iron guanidinate complexes and formation of a novel dinuclear iron(ii) species with a dianionic μ-η2∶η2 (biguanidinate) ligand
4. Mono- and Dianionic Guanidinate Ligands. Reactivity of [iPrNC(NiPr)2]Ta(NMe2)3 and [(iPrNH)C(NiPr)2]TaCl(NMe2)3 with Me3SiCl and ArNC (Ar = 2,6-Me2C6H4)
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