Superelectrophilic Intermediates in Nitrogen-Directed Aromatic Borylation-Reference-Cited by-同舟云学术

Superelectrophilic Intermediates in Nitrogen-Directed Aromatic Borylation

Published:2009-09-28 Issue:41 Volume:131 Page:14679-14687
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

De Vries Timothy S.¹,Prokofjevs Aleksandrs¹,Harvey Jeremy N.¹,Vedejs Edwin¹

Affiliation:

1. Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, and School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS, United Kingdom

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja905369n

Reference128 articles.

1. The chemistry of borinium and borenium ions

2. Polar and free-radical halogenation of amine-boranes with halocarbons

3. Tricoordinate diphenylboron cation prepared in solution

4. Superelectrophiles

5. bThe definition of “superelectrophile” stated in the Olah review specifies that dicationic species are superelectrophiles, but the discussion also identifies several factors that enhance the electrophilicity of neutral or monocationic species. Explicit examples in Olah’s review include Lewis acid complexes of boric acid, trimethyl borate, and boron trichloride. In this usage, “superelectrophilicity” may be understood more broadly as a qualitative comparison between an exceptionally enhanced electrophile and the unenhanced parent electrophile.

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