The Monoanionic π-Radical Redox State of α-Iminoketones in Bis(ligand)metal Complexes of Nickel and Cobalt
Author:
Affiliation:
1. Max-Planck-Institut für Bioanorganische Chemie, Stiftstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic7008094
Reference52 articles.
1. Synthesis and Characterization of 1-Iminopropan-2-one and 2-Iminobutan-3-one Compounds, RC(O)C(NR')R
2. Preparation and Properties of Carbonyliron Complexes of 1-Aza-4-oxa-1,3-butadiene (α-Imino Ketone) – X-ray Crystal Structures of Fe(CO)3[MeNC(Ph)C(Ph)=O] and Fe2(CO)4[tBuNC(H)(Me)C(O)(O)C(Me)C(H)=NtBu]
3. Cationic olefin Pd(II) complexes bearing α-iminoketone N,O-ligands: synthesis, intramolecular and interionic characterization and reactivity with olefins and alkynes
4. Reactivity of 1-aza-4-oxa-1,3-butadienes (.alpha.-imino ketones) toward triorganoaluminum reagents. 1. X-ray crystal structures of [(AlMe3)2{.sigma.,.sigma.-N,O-(MeN:C(Ph)C(Ph):O)}] with a N,O-bridge-bonded .alpha.-imino ketone, and of cyclic Me2Al(tert-Bu)N:CHC(Me)2OAlMe3, a carbonyl alkylated product which is O-coordinated to AlMe3
5. MonodentateN coordination of 1aza4oxo1,3butadienes [R1NC(R2)C(R3)O] to platinum(II). X-ray structure of trans-[PtCl2(PEt3){σ-N-(t-BuNCHC(Me)O)}]
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