A Sterically Expanded “Constrained Geometry Catalyst” for Highly Active Olefin Polymerization and Copolymerization: An Unyielding Comonomer Effect
Author:
Affiliation:
1. Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja044678g
Reference21 articles.
1. Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst
2. Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solution
3. Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization
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