Regioselective Heck Couplings of α,β-Unsaturated Tosylates and Mesylates with Electron-Rich Olefins
Author:
Affiliation:
1. Department of Chemistry and the Interdisciplinary Nanoscience Center, University of Aarhus, Langelandsgade 140, 8000 Aarhus C, Denmark
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol052136d
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1. Catalytic asymmetric arylation of 2,3-dihydrofuran with aryl triflates
2. Palladium-catalyzed α-arylation of vinyl butyl ether with aryl halides
3. First examples of a tosylate in the palladium-catalyzed Heck cross coupling reaction
4. Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates
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