Computational Study on the Reaction Pathway of α-Bromoacetophenones with Hydroxide Ion: Possible Path Bifurcation in the Addition/Substitution Mechanism-Reference-Cited by-同舟云学术

Computational Study on the Reaction Pathway of α-Bromoacetophenones with Hydroxide Ion: Possible Path Bifurcation in the Addition/Substitution Mechanism

Published:2011-09-07 Issue:20 Volume:76 Page:8294-8299
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Itoh Shuhei¹,Yoshimura Nobuyoshi¹,Sato Makoto¹,Yamataka Hiroshi¹

Affiliation:

1. Department of Chemistry and the Research Center for Smart Molecules, Rikkyo University, Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo201485y

Reference45 articles.

1. The Effect of the Carbonyl and Related Groups on the Reactivity of Halides in SN2 Reactions

2. The reactivity of 2-bromo-1-phenylethanone (phenacyl bromide) toward nucleophilic species

3. Mechanism of the Reaction of α-Haloketones with Weakley Basic Nucleophilic Reagents

4. The .alpha.- and .beta.-carbon substituent effect on SN2 reactivity. A valence-bond approach

5. Group transfers. 1. Enolate structures contributing to the transition state for nucleophilic substitution on .alpha.-substituted carbonyl compounds

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