Reactivity of Phosphate Monoester Monoanions in Aqueous Solution. 1. Quantum Mechanical Calculations Support the Existence of “Anionic Zwitterion” MeO+(H)PO32- as a Key Intermediate in the Dissociative Hydrolysis of the Methyl Phosphate Anion1-Reference-Cited by-同舟云学术

Reactivity of Phosphate Monoester Monoanions in Aqueous Solution. 1. Quantum Mechanical Calculations Support the Existence of “Anionic Zwitterion” MeO+(H)PO32- as a Key Intermediate in the Dissociative Hydrolysis of the Methyl Phosphate Anion1

Published:2002-05-31 Issue:25 Volume:124 Page:7573-7587
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Bianciotto Marc¹,Barthelat Jean-Claude¹,Vigroux Alain¹

Affiliation:

1. Contribution from the Laboratoire de Synthèse et Physico-Chimie de Molécules d'Intérêt Biologique (UMR 5068), and Laboratoire de Physique Quantique, IRSAMC (UMR 5626), Université Paul Sabatier, 118 Route de Narbonne, 31062 Toulouse Cedex 4, France

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0200948

Reference38 articles.

1. Why Nature Chose Phosphates

2. Mechanistic alternatives in phosphate monoester hydrolysis: What conclusions can be drawn from available experimental data?

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