Synthesis of Arenethiolate Complexes of Divalent and Trivalent Lanthanides from Metallic Lanthanides and Diaryl Disulfides: Crystal Structures of [{Yb(hmpa)3}2(μ-SPh)3][SPh] and Ln(SPh)3(hmpa)3 (Ln = Sm, Yb; hmpa = Hexamethylphosphoric Triamide)
Author:
Affiliation:
1. Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka 560, Japan, and Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, Osaka 560, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic950050i
Reference47 articles.
1. Facile formation of lanthanoid(III) thiolates from benzophenone-catalyzed reaction of lanthanoid metals and disulfides, and their use as sulfenylating reagents
2. Pyridine Coordination Complexes of the Divalent Ytterbium Chalcogenolates Yb(EPh)2 (E = S, Se, Te)
3. Lanthanide thiolate complexes; synthesis of [Ln{N(SiMe3)2}(µ-SBut)]2(Ln = Eu, Gd, Y) and the X-ray crystal structure of the Gd complex
4. Synthesis and structures of homoleptic 2-methylpropane-2-thiolate complexes of samarium and ytterbium
5. Ferrocenhaltige Liganden in der Lanthanid-Chemie: Alkoxide und Thiolate
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