Formation, Reactivity, and Photorelease of Metal Bound Nitrosyl in [Ru(trpy)(L)(NO)]n+ (trpy = 2,2′:6′,2′′-Terpyridine, L = 2-Phenylimidazo[4,5-f]1,10-phenanthroline)-Reference-Cited by-同舟云学术

Formation, Reactivity, and Photorelease of Metal Bound Nitrosyl in [Ru(trpy)(L)(NO)]n+ (trpy = 2,2′:6′,2′′-Terpyridine, L = 2-Phenylimidazo[4,5-f]1,10-phenanthroline)

Published:2008-03-01 Issue:8 Volume:47 Page:3218-3227
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Maji Somnath¹,Sarkar Biprajit¹,Patra Malay¹,Das Atanu Kumar¹,Mobin Shaikh M.¹,Kaim Wolfgang¹,Lahiri Goutam Kumar¹

Affiliation:

1. Department of Chemistry, Indian Institute of Technology—Bombay, Powai, Mumbai 400076, India, and Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70550 Stuttgart, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic702160w

Reference83 articles.

1. New Ruthenium Nitrosyl Complexes with Tris(1-pyrazolyl)methane (tpm) and 2,2‘-Bipyridine (bpy) Coligands. Structure, Spectroscopy, and Electrophilic and Nucleophilic Reactivities of Bound Nitrosyl

2. The Metal−NO Interaction in the Redox Systems [Cl5Os(NO)]n-, n = 1−3, and cis-[(bpy)2ClOs(NO)]2+/+: Calculations, Structural, Electrochemical, and Spectroscopic Results

3. Establishing the NO oxidation state in complexes [Cl5(NO)M]n−, M = Ru or Ir, through experiments and DFT calculations

4. Metallonitrosyl Fragment as Electron Acceptor: Intramolecular Charge Transfer, Long Range Electronic Coupling, and Electrophilic Reactivity in the trans-[NCRu(py)4(CN)Ru(py)4NO]3+ Ion

5. Basicity of Coordinated Pyrazine and Bonding Interactions with [MII(CN)5]3- Fragments (M = Fe, Ru, Os)

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