Reaction of [Cp2(CO)3Mo2(μ-η2-P2)(PPh2)]- with the Cumulenes 3-ClC6H4NCO, PhNCS, and CS2 and with Michael Acceptors: Synthesis and Reactivity of [Cp2(CO)3Mo2(μ-η3-Ph2PC(H)SP2S)], a Complex Containing an Unusual CSP2S Five-Membered Ring-Reference-Cited by-同舟云学术

Reaction of [Cp2(CO)3Mo2(μ-η2-P2)(PPh2)]- with the Cumulenes 3-ClC6H4NCO, PhNCS, and CS2 and with Michael Acceptors: Synthesis and Reactivity of [Cp2(CO)3Mo2(μ-η3-Ph2PC(H)SP2S)], a Complex Containing an Unusual CSP2S Five-Membered Ring

Published:2000-02-17 Issue:6 Volume:19 Page:984-993
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Davies John E.¹,Feeder Neil¹,Mays Martin J.¹,Tompkin Peter K.¹,Woods Anthony D.¹

Affiliation:

1. Department of Chemistry, Lensfield Road, Cambridge CB2 1EW, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om990729k

Reference31 articles.

1. Transition-metal-substituted phosphanes, arsanes and stibanes, LXIII.

2. Insertion of Diazoacetic Ester into the P–H Bond of the Cationic Primary and Secondary Phosphane-Substituted Iron Complexes [Cp(OC)2Fe–P(Ph)(R)H]+ (R = Ph, Me) and [(R′C5H4)(OC)2Fe–P(R)H2]+ [R =tBu, Ph, Mes; R′= H, Neomenthyl (NM)]

3. Reactivity of CS2towards the anion [Mo2Cp2(CO)3(PPh2)(µ-η2-P2)]–; synthesis and charactrisation of [Mo2Cp2(CO)3{µ-η3-Ph2PC(H)SP2S}], a complex containing an unusual CSP2S ring

4. Cp2Mo2(CO)4P2 as Complex Ligand

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