The C7H10 Potential Energy Landscape: Concerted Transition States and Diradical Intermediates for the Retro-Diels−Alder Reaction and [1,3] Sigmatropic Shifts of Norbornene
Author:
Affiliation:
1. Contribution from the Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9818250
Reference52 articles.
1. Subjacent orbital control. Electronic factor favoring concertedness in Woodward-Hoffmann forbidden reactions
2. Stereochemistry of the thermal rearrangement of bicyclo[3.2.0]hept-2-ene to bicyclo[2.2.1]hept-2-ene (norbornene). [1,3] Carbon migration with predominant inversion
3. Temperature dependence of stereoselectivity as a criterion for mechanism. Rearrangement of bicyclo[2.1.1]hexene-5-d and two phenyl derivatives
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