1. Biogeochemistry and Environmental Analytical Chemistry Research Group, School of Earth, Ocean and Environmental Sciences, University of Plymouth, Drake Circus, Plymouth PL4 8AA, U.K., Williamson Research Centre for Molecular Environmental Science, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester M13 9PL, U.K., and Centre for Radiochemistry Research, School of Chemistry, University of Manchester, Manchester M13 9PL., U.K.