Quantum Chemical Study on Ethylene Addition to (O═)2Os(═NH)2 and (O═)2Os(═NH)-cyclo-(−NHCH2CH2HN−) as Model Complexes for the Osmium-Catalyzed Aminohydroxylation of Olefins
Author:
Affiliation:
1. Fachbereich Chemie der Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35043 Marburg, Germany
2. Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005-1892
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om900986b
Reference44 articles.
1. Catalytic Asymmetric Aminohydroxylation(AA) of Olefins
2. Zur Kenntnis der organischen Osmium-Verbindungen. II. Mitteilung
3. Asymmetric induction in the reaction of osmium tetroxide with olefins
4. Asymmetric dihydroxylation via ligand-accelerated catalysis
5. Theoretische Untersuchungen schließen eine [2 + 2]-Addition als einleitenden Schritt der Osmiumtetroxid-katalysierten Dihydroxylierung von Alkenen aus
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