Iridium Olefin Complexes Bearing Dialkylamino/amido PNP Pincer Ligands: Synthesis, Reactivity, and Solution Dynamics
Author:
Affiliation:
1. Department Chemie, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching b. München, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om800423u
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3. Distinct Thermodynamics for the Formation and Cleavage of N−H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex
4. Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex
5. Reactions of Anilines and Benzamides with a 14-Electron Iridium(I) Bis(phosphinite) Complex: N−H Oxidative Addition versus Lewis Base Coordination
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