Relationships between the Electrophilicity Index and Experimental Rate Coefficients for the Aminolysis of Thiolcarbonates and Dithiocarbonates-Reference-Cited by-同舟云学术

Relationships between the Electrophilicity Index and Experimental Rate Coefficients for the Aminolysis of Thiolcarbonates and Dithiocarbonates

Published:2005-02-01 Issue:5 Volume:70 Page:1754-1760
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Campodónico Paola R.¹,Fuentealba Patricio¹,Castro Enrique A.¹,Santos José G.¹,Contreras Renato¹

Affiliation:

1. Departmento de Física, Facultad de Ciencias, Universidad de Chile, Casilla 653-Santiago, Chile, Facultad de Química, Pontificia Universidad Católica de Chile, Casilla 6177, Santiago, Chile, and Departmento de Química, Facultad de Ciencias, Universidad de Chile, Casilla 653-Santiago, Chile

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo048127k

Reference53 articles.

1. Mechanism of the aminolysis of acetate esters

2. Ester aminolysis. Partitioning of the tetrahedral addition intermediate, T.+-., and the relative leaving ability of nitrogen and oxygen

3. Effect of nucleophile basicity on intramolecular nucleophilic aminolysis reactions of carbonate diesters

4. Novel catalysis of o-nitrophenyl carbonates by p-dimethlaminonopyridine

5. Curved Broensted plot in pyridinolysis of 2,4-dinitrophenyl methyl carbonate. Comparison of leaving group abilities between pyridines and phenolates

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