The 18-Electron, Metal−Metal-Bonded Dimers [η5-C5Ph5Fe(CO)2]2 and [η5-C5Ph4(p-tolyl)Fe(CO)2]2: Their Proclivity To Undergo Spontaneous, Thermal Homolysis to the Corresponding 17-Electron Monomers
Author:
Affiliation:
1. Department of Chemistry, Queen's University, Kingston, Ontario, Canada K7L 3N6
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om960323x
Reference88 articles.
1. Seventeen-electron metal-centered radicals
2. (b) Trogler, W. C., Ed.Organometallic Radical Processes; J. Organomet. Chem. Library 22; Elsevier: New York, 1990; p 49 and references therein.
3. Equilibrium between [CpCr(CO)3]2 and CpCr(CO)3. Thermodynamics of chromium-chromium single-bond cleavage
4. An investigation of the homolytic dissociation of [.eta.5-C5Me5Cr(CO)3]2 and related complexes. The role of ligand substitution on the solution thermochemistry of metal-metal bond cleavage
5. Unusual structural and magnetic resonance properties of dicyclopentadienylhexacarbonyldichromium
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