Reversible Twisting of Primary Amides via Ground State N–C(O) Destabilization: Highly Twisted Rotationally Inverted Acyclic Amides
Author:
Affiliation:
1. Department of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States
2. Department of Chemistry, Wroclaw University, F. Joliot-Curie 14, Wroclaw 50-383, Poland
Funder
Division of Chemistry
Rutgers, The State University of New Jersey
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.7b11309
Reference92 articles.
1. Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate
2. A New Twist on Amide Solvolysis
3. “Amide Resonance” Correlates with a Breadth of C−N Rotation Barriers
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