Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV–Oxo Intermediate

Author:

Fan Ruixi1,Serrano-Plana Joan2,Oloo Williamson N.3,Draksharapu Apparao3,Delgado-Pinar Estefanía4,Company Anna2,Martin-Diaconescu Vlad2ORCID,Borrell Margarida2,Lloret-Fillol Julio5,García-España Enrique4,Guo Yisong1ORCID,Bominaar Emile L.1ORCID,Que Lawrence3ORCID,Costas Miquel2ORCID,Münck Eckard1ORCID

Affiliation:

1. Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States

2. Grup de Química Bioinspirada, Supramolecular i Catàlisi (QBIS-CAT), Institut de Química Computacional i Catàlisi (IQCC), Departament de Química, Universitat de Girona, C/M. Aurèlia Capmany 69, 17003 Girona, Catalonia, Spain

3. Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States

4. Grup de Química Supramolecular, Institut de Ciència Molecular, Departament de Química Inorgànica, Universitat de València, 46980 Paterna, Valencia, Spain

5. Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Avinguda Països Catalans 16, 43007 Tarragona, Spain

Funder

Division of Chemistry

Generalitat Valenciana

Ministerio de Econom?a y Competitividad

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

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