Cyclopropylcarbinyl-to-Homoallyl Carbocation Equilibria Influence the Stereospecificity in the Nucleophilic Substitution of Cyclopropylcarbinols
Author:
Affiliation:
1. Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, New Jersey 07102, United States
Funder
Nanjing Institute of Technology
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.3c00257
Reference43 articles.
1. Nucleophilic Substitution at Quaternary Carbon Stereocenters
2. Correction to “Nucleophilic Substitution at Quaternary Carbon Stereocenters”
3. Small-Ring Compounds. IV. Interconversion Reactions of Cyclobutyl, Cyclopropylcarbinyl and Allylcarbinyl Derivatives
4. Solvolysis and degenerate cyclopropylcarbinyl-cyclopropylcarbinyl rearrangement of a hexamethylcyclopropylcarbinyl system
5. The Cyclopropylcarbinyl-Cyclobutyl-Homoallylic Rearrangement. Part III. Evidence for a symmetrical intermediate and for two discrete rearrangement processes
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