Controlled Evolution of the Cope Rearrangement: Transition from Concerted to Interrupted and Aborted Pericyclic Reactions Regulated by a Switch Built from an Intramolecular Frustrated Lewis Pair-Reference-Cited by-同舟云学术

Controlled Evolution of the Cope Rearrangement: Transition from Concerted to Interrupted and Aborted Pericyclic Reactions Regulated by a Switch Built from an Intramolecular Frustrated Lewis Pair

Published:2019-10-16 Issue:22 Volume:84 Page:14844-14853
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Vidhani Dinesh V.¹,Alabugin Igor V.²^ORCID

Affiliation:

1. University of Wisconsin, La Crosse, Wisconsin 54601, United States

2. Florida State University, Tallahassee, Florida 32306, United States

Funder

National Science Foundation

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.9b02633

Reference92 articles.

1. Bioactivity-Guided Navigation of Chemical Space

2. The Baldwin rules: revised and extended

3. Reaction mechanisms: pericyclic reactions

4. Cope Rearrangement of 1,5-Hexadiene: Full Geometry Optimizations Using Analytic MR-CISD and MR-AQCC Gradient Methods

5. The Cope Rearrangement Transition Structure Is Not Diradicaloid, but Is It Aromatic?

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