Stabilization of NaBH4 in Methanol Using a Catalytic Amount of NaOMe. Reduction of Esters and Lactones at Room Temperature without Solvent-Induced Loss of Hydride-Reference-Cited by-同舟云学术

Stabilization of NaBH4 in Methanol Using a Catalytic Amount of NaOMe. Reduction of Esters and Lactones at Room Temperature without Solvent-Induced Loss of Hydride

Published:2018-01-17 Issue:3 Volume:83 Page:1431-1440
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

C. P. Prasanth¹,Joseph Ebbin¹,A Abhijith¹,D. S. Nair¹,Ibnusaud Ibrahim¹,Raskatov Jevgenij²,Singaram Bakthan²^ORCID

Affiliation:

1. Institute for Intensive Research in Basic Sciences, Mahatma Gandhi University, P.D. Hills P. O., Kottayam, Kerala 686560, India

2. Department of Chemistry and Biochemistry, University of California, Santa Cruz, 1156 High Street, Santa Cruz, California 95064, United States

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.7b02993

Reference46 articles.

1. Practical Procedure for the Chemoselective Reduction of Esters by Sodium Borohydride. Effect of the Slow Addition of Methanol

2. Reduction of DDHQ and TCC esters by NaBH4-its specificity in the presence of Alkyl/Aryl esters

3. Large-Scale Carbonyl Reductions in the Pharmaceutical Industry

4. Selective Aldehyde Reduction in Ketoaldehydes with NaBH4-Na2CO3-H2O at Room Temperatures

5. Synthesis of 3,4-Fused γ-Lactone-γ-Lactam Bicyclic Moieties as Multifunctional Synthons for Bioactive Molecules

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