Enantiodivergent Synthesis of Tertiary α-Aryl 1-Indanones: Evidence Toward Disparate Mechanisms in the Palladium-Catalyzed Decarboxylative Asymmetric Protonation
Author:
Affiliation:
1. Synthesis and Solid State Pharmaceutical Centre, Centre for Synthesis and Chemical Biology, School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland
Funder
Science Foundation Ireland
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.7b00303
Reference57 articles.
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3. Palladium-catalyzed cleavage of prochiral enol carbonates: Enantioselective ketonisation of resulting enols
4. Production of optically active ketones by a palladium-induced cascade reaction from racemic β-ketoesters.
5. Asymmetric protonation of enolic species: dramatic increase in the selectivity with temperature and unexpected Eyring diagram
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