Formal γ-C(sp3)–H Activation of Ketones via Microwave-Promoted and Iminyl-Radical-Mediated 1,5-Hydrogen Atom Transfer
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602, United States
Funder
Division of Chemistry
Brigham Young University
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.3c00915
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1. Enamine Chemistry I. Carbanion Alkylations
2. γ-Alkylation of unsaturated ketones and esters: zinc bromide-catalysed alkylation of O-silylated dienolates
3. Metalated unsaturated amides. Regio- and stereoselective .gamma.-alkylation
4. Conceptually New Directed Aldol Condensation Using Aluminum Tris(2,6-diphenylphenoxide)
5. Radical-Mediatedγ-Functionalizations ofα,β-Unsaturated Carboxylic Amides
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