π-Facial Stereoselectivity in Acyl Nitroso Cycloadditions to 5,5-Unsymmetrically Substituted Cyclopentadienes: Computational Exploration of Origins of Selectivity and the Role of Substituent Conformations on Selectivity-Reference-Cited by-同舟云学术

π-Facial Stereoselectivity in Acyl Nitroso Cycloadditions to 5,5-Unsymmetrically Substituted Cyclopentadienes: Computational Exploration of Origins of Selectivity and the Role of Substituent Conformations on Selectivity

Published:2021-11-16 Issue:23 Volume:86 Page:17082-17089
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Zhao Fengyue¹,Yu Peiyuan²^ORCID,Chen Yu¹,Liu Fang¹^ORCID,Houk K. N.³^ORCID

Affiliation:

1. College of Sciences, Nanjing Agricultural University, Nanjing, Jiangsu 210095, China

2. Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China

3. Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States

Funder

Natural Science Foundation of Jiangsu Province

US National Science Foundation

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.1c02191

Reference45 articles.

1. Total Synthesis of VM55599. Utilization of an Intramolecular Diels−Alder Cycloaddition of Potential Biogenetic Relevance

2. The Diels-Alder Reaction in Total Synthesis

3. Chemistry and Biology of Biosynthetic Diels–Alder Reactions

4. Origins of Regioselectivity of Diels−Alder Reactions for the Synthesis of Bisanthraquinone Antibiotic BE-43472B

5. Probing Substituent Effects in Aryl−Aryl Interactions Using Stereoselective Diels−Alder Cycloadditions

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