Pd-Catalyzed Alkene Diamination Reactions with O-Benzoylhydroxylamine Electrophiles: Evidence Supporting a Pd(II/IV) Catalytic Cycle, the Role of 2,4-Pentanedione Derivatives as Ligands, and Expanded Substrate Scope-Reference-Cited by-同舟云学术

Pd-Catalyzed Alkene Diamination Reactions with O-Benzoylhydroxylamine Electrophiles: Evidence Supporting a Pd(II/IV) Catalytic Cycle, the Role of 2,4-Pentanedione Derivatives as Ligands, and Expanded Substrate Scope

Published:2021-08-04 Issue:17 Volume:86 Page:11378-11387
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Kirsch Janelle K.¹,Gonzalez Gabriel A.¹,Faculak Mason S.¹,Wolfe John P.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Michigan, 930 N. University Avenue, Ann Arbor, Michigan 48109-1055, United States

Funder

Horace H. Rackham School of Graduate Studies, University of Michigan

National Institute of General Medical Sciences

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.1c00877

Reference48 articles.

1. Transition-Metal-Catalyzed Diamination of Olefins

2. Methods for direct alkene diamination, new & old

3. Synthesis of Saturated Heterocycles via Metal-Catalyzed Alkene Diamination, Aminoalkoxylation, or Dialkoxylation Reactions

4. Development of Intramolecular Vicinal Diamination of Alkenes: From Palladium to Bromine Catalysis

5. Intramolecular Oxidative Palladium-Catalyzed Amination Involving Double C–H Functionalization of Unactivated Olefins

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