Catalytic Methylene Insertion between Amines and Terminal Alkynes via C–N Bond Cleavage of <i>N</i>,<i>N</i>-Dimethylacetamide: A Unique Route to Propargylic Amines-Reference-Cited by-同舟云学术

Catalytic Methylene Insertion between Amines and Terminal Alkynes via C–N Bond Cleavage of N,N-Dimethylacetamide: A Unique Route to Propargylic Amines

Published:2023-01-16 Issue:3 Volume:88 Page:1884-1889
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Rahaman Ajijur¹²,Shinde Rupali Dasharath¹²,Bhadra Sukalyan¹²^ORCID

Affiliation:

1. Inorganic Materials and Catalysis Division, CSIR-Central Salt and Marine Chemicals Research Institute, G.B. Marg, Bhavnagar 364002, Gujarat, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

Funder

Council of Scientific and Industrial Research, India

University Grants Commission

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.2c02584

Reference51 articles.

1. Transition-Metal-Catalyzed Cleavage of C–N Single Bonds

2. Bond Dissociation Energies of Organic Molecules

3. A New Combined Source of “CN” from N,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C−H Bonds

4. Copper-Mediated Cyanation of Aryl Halide with the Combined Cyanide Source

5. Direct Transformation of N,N-Dimethylformamide to −CN: Pd-Catalyzed Cyanation of Heteroarenes via C–H Functionalization

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