Copper-Catalyzed Regioselective and Stereoselective Coupling of Grignard Reagents with Pent-1-en-4-yn-3-yl Benzoates: A Shortcut to (Z)-1,5-Disubstituted Pent-3-en-1-ynes from Accessible Starting Materials-Reference-Cited by-同舟云学术

Copper-Catalyzed Regioselective and Stereoselective Coupling of Grignard Reagents with Pent-1-en-4-yn-3-yl Benzoates: A Shortcut to (Z)-1,5-Disubstituted Pent-3-en-1-ynes from Accessible Starting Materials

Published:2018-10-18 Issue:22 Volume:83 Page:14158-14164
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Chen Fenglin¹²³,Chen Yanjiao¹²,Cao Hongen¹²,Xu Qing²^ORCID,Yu Lei¹²^ORCID

Affiliation:

1. Jiangsu Key Laboratory of Zoonosis, Yangzhou University, Yangzhou 225009, China

2. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

3. School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Funder

Government of Jiangsu Province

National Natural Science Foundation of China

Priority Academic Program Development of Jiangsu Higher Education Institutions

Jiangsu Key Laboratory of Zoonosis, Yangzhou University

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.8b02275

Reference44 articles.

1. Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu–Allenyl Intermediates

2. Catalytic, Enantioselective Synthesis of Allenyl Boronates

3. Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction

4. Cu(I)-Catalyzed Synthesis of Furan-Substituted Allenes by Use of Conjugated Ene-yne Ketones as Carbene Precursors

5. Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

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