Domino Fragmentations in Traceless Directing Groups of Radical Cascades: Evidence for the Formation of Alkoxy Radicals via C–O Scission
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, United States
Funder
Division of Chemistry
International Business Machines Corporation
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.6b01052
Reference52 articles.
1. Traceless Directing Groups in Radical Cascades: From Oligoalkynes to Fused Helicenes without Tethered Initiators
2. Design of Leaving Groups in Radical CC Fragmentations: Through-Bond 2c-3e Interactions in Self-Terminating Radical Cascades
3. Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems
4. From a Remarkable Manifestation of Polar Effects in a Radical Fragmentation to the Convergent Synthesis of Highly Functionalized Ketones
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