A Quantitative Analysis of Factors Influencing Ease of Formation and σ-Bonding Strength of Oxa- and Thia-N-Heterocyclic Carbenes
Author:
Affiliation:
1. School of Chemical and Physical Sciences, Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG, United Kingdom
2. Laboratory of Molecular Modelling, National Medicines Institute, 30/34 Chełmska Street, 00-725 Warsaw, Poland
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.7b02283
Reference48 articles.
1. Quantitative Index of the Relative Ease of Formation and σ-Bonding Strength of N-Heterocyclic Carbenes
2. A Correlation of Reaction Rates
3. Switching the Electron‐Donor Properties of N‐Heterocyclic Carbenes by a Facile Deprotonation Strategy
4. Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for further derivatization
5. Facile Derivatization of a “Chemo-active” NHC Incorporating an Enolate Backbone and Relevant Tuning of Its Electronic Properties
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