Does the Reaction of Cyclopropyl Acid Chlorides and Imines To Form 1,3-Oxazin-4-enone Heterocycles Proceed via a Ketene or an N-Acyl-iminium Mechanism?
Author:
Affiliation:
1. Department of Chemistry, University of Otago, Dunedin 9054, New Zealand
Funder
University of Otago
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.0c00229
Reference29 articles.
1. 5-Phenylthio-1,3-oxazinan-4-ones via hetero Diels–Alder reactions: synthesis of (R)- and (S)-Duloxetines and Fluoxetines
2. Simons, J. Fortune Magazine 2004, accessible at https://archive.fortune.com/magazines/fortune/fortune_archive/2004/06/28/374398/index.htm.
3. Reaction of 2,2-dimethyl-1,3-dioxin-4-ones with imines, carbodiimides, and isocyanates.
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1. One-pot synthesis of 1,3-oxazin-4-ones through an Ir-catalyzed mild formal condensation reaction of secondary amides with acyl chlorides;Organic Chemistry Frontiers;2023
2. Tandem CuAAC/Ring Cleavage/[4 + 2] Annulation Reaction to Synthesize Dihydrooxazines and Conversion to 2-Aminopyrimidines;Organic Letters;2021-12-22
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