Utilization of the Thorpe–Ingold Effect in the Synthesis of Cyclooctanoid Ring Systems via Anionic 6-exo-dig Cyclization/Claisen Rearrangement Sequence-Reference-Cited by-同舟云学术

Utilization of the Thorpe–Ingold Effect in the Synthesis of Cyclooctanoid Ring Systems via Anionic 6-exo-dig Cyclization/Claisen Rearrangement Sequence

Published:2020-07-20 Issue:15 Volume:85 Page:9464-9474
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

DeLomba Weston C.¹,Stone Elizabeth A.¹^ORCID,Alley Kimberly A.¹^ORCID,Iannarone Victoria¹,Tarsis Emily¹,Ovaska Sami¹,Ovaska Timo V.¹^ORCID

Affiliation:

1. Department of Chemistry, Connecticut College, 270 Mohegan Avenue, New London, Connecticut 06320, United States

Funder

National Institutes of Health

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.0c01132

Reference37 articles.

1. Progress in the Construction of Cyclooctanoid Systems: New Approaches and Applications to Natural Product Syntheses

2. Recent Advances in the Total Synthesis of Natural Products Containing Eight-Membered Carbocycles (2009–2019)

3. The synthesis of carbocyclic eight-membered rings

4. Total synthesis of the marine sesquiterpenes dactylol and africanol. De novo construction of a cyclooctanoid natural product from cycloheptane precursors

5. Total synthesis of epi-precapnelladiene

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