Computationally Probing the Mechanism of the Blue-Light-Driven O–H Functionalization of Alcohols by Aryldiazoacetates: Photobasicity or Carbene Chemistry
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, California State University─Fullerton, Fullerton, California 92834-6866, United States
Funder
American Chemical Society Petroleum Research Fund
National Science Foundation
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.2c00442
Reference40 articles.
1. Developments in the Photochemistry of Diazo Compounds
2. Photochemical transformations of diazocarbonyl compounds: expected and novel reactions
3. Ultrafast Carbonylcarbene Formation and Spin-Equilibration
4. Solvent Dependence of the 2-Naphthyl(carbomethoxy)carbene Singlet−Triplet Energy Gap
5. Reversible Interconversion between Singlet and Triplet 2-Naphthyl(carbomethoxy)carbene
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2. Visible light-mediated photolysis of organic molecules: the case study of diazo compounds;Chemical Communications;2023
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