Investigation of the Stereochemical Mechanism of the Nucleophilic Substitution Reaction at Pentacoordinate Phosphorus of Spirophosphorane
Author:
Affiliation:
1. Green Catalysis Center, College of Chemistry, Zhengzhou University, Kexue Road No. 100, Zhengzhou 450001, China
2. Institute Drug Discovery Technology, Ningbo University, Ningbo, Zhejiang 315211, China
Funder
National Natural Science Foundation of China
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.0c02953
Reference45 articles.
1. The Pentacovalent Phosphorus Intermediate of a Phosphoryl Transfer Reaction
2. The modern interpretation of the Wittig reaction mechanism
3. Biphilic Organophosphorus-Catalyzed Intramolecular Csp2–H Amination: Evidence for a Nitrenoid in Catalytic Cadogan Cyclizations
4. Non-dissociative permutation of a stable hydrophosphorane and retention of stereochemistry of the electrophilic reaction of its conjugate phosphoranide base
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