Regioselective Hydroxylation of Unsymmetrical Ketones Using Cu, H<sub>2</sub>O<sub>2</sub>, and Imine Directing Groups via Formation of an Electrophilic Cupric Hydroperoxide Core-Reference-Cited by-同舟云学术

Regioselective Hydroxylation of Unsymmetrical Ketones Using Cu, H₂O₂, and Imine Directing Groups via Formation of an Electrophilic Cupric Hydroperoxide Core

Published:2024-02-07 Issue:4 Volume:89 Page:2622-2636
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Zhang Shuming¹,Goswami Sunipa¹,Schulz Karl H. G.¹^ORCID,Gill Karan¹,Yin Xinyi¹,Hwang Jimin¹,Wiese Jasmine¹,Jaffer Isabel¹,Gil Roberto R.¹^ORCID,Garcia-Bosch Isaac¹^ORCID

Affiliation:

1. Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States

Funder

National Institute of General Medical Sciences

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.3c02647

Reference37 articles.

1. Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )−H Bonds in Natural Products

2. If CH Bonds Could Talk: Selective CH Bond Oxidation

3. A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

4. Transient imines as ‘next generation’ directing groups for the catalytic functionalisation of C–H bonds in a single operation

5. Transient imine directing groups for the C–H functionalisation of aldehydes, ketones and amines: an update 2018–2020

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1. Expanding the Clip-and-Cleave Concept: Approaching Enantioselective C–H Hydroxylations by Copper Imine Complexes Using O₂ and H₂O₂ as Oxidants;Journal of the American Chemical Society;2024-09-06