Directed Synthesis of Crystalline Plutonium(III) and (IV) Oxalates: Accessing Redox-Controlled Separations in Acidic Solutions
Author:
Affiliation:
1. Chemistry Division
2. Plutonium Manufacturing and Technology Division
3. Materials Physics and Applications Division
4. Los Alamos National Laboratory, Los Alamos, New Mexico 87545
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic900344u
Reference52 articles.
1. Plutonium Handbook: A Guide to the Technology; ed.Wick, O. J., Ed.American Nuclear Society:LaGrange Park, IL, 1980; Vols.1and2, p966.
2. U(IV)/Ln(III) mixed site in polymetallic oxalato complexes. Part III: Structure of Na[Yb(C2O4)2(H2O)]·3H2O and the derived quadratic series (NH4+)1−x[Ln1−xUx (C2O4)2(H2O)]·(3+x) H2O, Ln=Y, Pr–Sm, Gd, Tb
3. Synthesis and crystal structure of La(H2O)(C2O4)2·(CN3H6) and of [Nd(H2O)]2(C2O4)4·(NH4)(CN3H6)
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