1. Department of Chemistry, Washington State University, P.O. Box 644630, Pullman, Washington 99164-4630, Department of Geosciences and the Earth & Environmental Systems Institute, 503 Deike Building, The Pennsylvania State University, University Park, Pennsylvania 16802, and Center for Environmental and Molecular Science (CEMS), Department of Geosciences, 255 Earth and Space Sciences Building, Stony Brook University, Stony Brook, New York 11794-2100