Fluxional η3-Allyl Derivatives of ansa-Scandocenes and an ansa-Yttrocene. Measurements of the Barriers for the η3 to η1 Process as an Indicator of Olefin Binding Energy to d0 Metallocenes
Author:
Affiliation:
1. Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om980893s
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1. Allyl complexes of dicyclopentadienyl-niobium(III) and -tantalum(III)
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3. Synthesis and reactivity of permethyltantalocene derivatives processing .eta.3-allyl, .eta.2-butadiene, .eta.2-methylallene, and .eta.1-alkenylidene ligands. Model studies for the role of surface vinylidenes in the Fischer-Tropsch hydrocarbon-chain-lengthening process
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