Trigonal-Planar versus Pyramidal Geometries in the Tris(ring) Heteroleptic Divalent Lanthanide Complexes (C5Me5)Ln(μ-η6:η1-Ph)2BPh2: Crystallographic and Density Functional Theory Analysis-Reference-Cited by-同舟云学术

Trigonal-Planar versus Pyramidal Geometries in the Tris(ring) Heteroleptic Divalent Lanthanide Complexes (C5Me5)Ln(μ-η6:η1-Ph)2BPh2: Crystallographic and Density Functional Theory Analysis

Published:2009-10-02 Issue:20 Volume:28 Page:6073-6078
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Evans William J.¹,Walensky Justin R.¹,Furche Filipp¹,DiPasquale Antonio G.²,Rheingold Arnold L.²

Affiliation:

1. Department of Chemistry, University of California, Irvine, California 92697-2025

2. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, MC 0358 La Jolla, California 92093-0358

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9006104

Reference39 articles.

1. Synthesis and Reactivity of Mono(pentamethylcyclopentadienyl) Tetraphenylborate Lanthanide Complexes of Ytterbium and Samarium: Tris(ring) Precursors to (C5Me5)Ln Moieties

2. Synthesis and crystallographic characterization of an unsolvated, monomeric samarium bis(pentamethylcyclopentadienyl) organolanthanide complex, (C5Me5)2Sm

3. Synthesis and x-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C5Me5)2Sm and (C5Me5)2Eu

4. Solid-State Structures of Base-Free Ytterbocenes and Inclusion Compounds of Bis(pentamethylcyclopentadienyl)ytterbium with Neutral Carboranes and Toluene: The Role of Intermolecular Contacts

5. Hydride bridges between LnCp2 centers

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