Mono-, Di-, and Trianionic β-Diketiminato Ligands: A Computational Study and the Synthesis and Structure of [(YbL)3(THF)], L = [{N(SiMe3)C(Ph)}2CH]-Reference-Cited by-同舟云学术

Mono-, Di-, and Trianionic β-Diketiminato Ligands: A Computational Study and the Synthesis and Structure of [(YbL)3(THF)], L = [{N(SiMe3)C(Ph)}2CH]

Published:2003-08-15 Issue:36 Volume:125 Page:10790-10791
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Eisenstein Odile¹,Hitchcock Peter B.¹,Khvostov Alexei V.¹,Lappert Michael F.¹,Maron Laurent¹,Perrin Lionel¹,Protchenko Andrey V.¹

Affiliation:

1. LSDSMS (UMR 5636), Université Montpellier 2, 34095, Montpellier Cedex 5, France, The Chemistry Laboratory, University of Sussex, Brighton, BN1 9QJ, UK, and Laboratoire de Physique Quantique - IRSAMC (UMR 5626), Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse, France

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja036902s

Reference26 articles.

1. Aspects of non-classical organolanthanide chemistry

2. The Chemistry of β-Diketiminatometal Complexes

3. Unusual crystalline heterobimetallic trinuclear β-diketiminates [Yb{L(µ-Li(thf)}2] and [Yb{L′(µ-Li(thf)}2]·thf [L, L′ = {N(SiMe3)C(R)}2CH, R = Ph, C6H4Ph-4]Electonic supplementary information (ESI) available: NOE data for 1 and NMR data for 2. See http://www.rsc.org/suppdata/cc/b2/b203321f/

4. Synthesis and reactivity of naphthalene complexes of ytterbium

5. Crystal data for1at 173 K: C67H95N6OSi6Yb3, FW = 1688.15, triclinic,P1̄,a= 13.4823(4),b= 16.3546(5),c= 20.0818(6) Å,α= 65.993(2)°,β= 84.086(2)°,γ= 86.355(2)°,V= 4022.3(2) Å3,Z= 2,ρcalcd= 1.39 Mg/m3, R1 = 0.040, wR2 = 0.103, GOF = 1.043.

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