Synthesis and Characterization of κ2C,N-N-Silyliminoacyl Tungsten Complexes Cp*(CO)2W{κ2C,N-C(R)═NSiR′3} [R = Me, Et, i-Pr, t-Bu; R′3 = (p-Tol)2Me, (p-Tol)3, Et3; Cp* = η5-C5Me5]: Thermally Induced Carbon−Carbon Bond Cleavage of Their Iminoacyl Ligands-Reference-Cited by-同舟云学术

Synthesis and Characterization of κ2C,N-N-Silyliminoacyl Tungsten Complexes Cp*(CO)2W{κ2C,N-C(R)═NSiR′3} [R = Me, Et, i-Pr, t-Bu; R′3 = (p-Tol)2Me, (p-Tol)3, Et3; Cp* = η5-C5Me5]: Thermally Induced Carbon−Carbon Bond Cleavage of Their Iminoacyl Ligands

Published:2010-03-17 Issue:7 Volume:29 Page:1839-1848
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Suzuki Eiji¹,Komuro Takashi¹,Kanno Yuto¹,Okazaki Masaaki²,Tobita Hiromi¹

Affiliation:

1. Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan

2. Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University, Hirosaki, Aomori 036-8560, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om901123w

Reference35 articles.

1. Catalytic reactions involving the cleavage of carbon–cyano and carbon–carbon triple bonds

2. Carbon−Carbon Bond Activation of R−CN (R = Me, Ar, iPr, tBu) Using a Cationic Rh(III) Complex

3. A Mechanistic Investigation of the Carbon−Carbon Bond Cleavage of Aryl and Alkyl Cyanides Using a Cationic Rh(III) Silyl Complex

4. C−C Bond Cleavage of Acetonitrile by a Carbonyl Iron Complex with a Silyl Ligand

5. Reactions of a Silyl(silylene)iron Complex with Nitriles: Carbon−Carbon Bond Cleavage of Nitriles by the Transiently Generated Disilanyliron(II) Intermediate

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