Intramolecular Rearrangements of Silenes. 3. From 2,5-Bis(1-methyl-1-silacyclobut-1-yl)-p-xylene to 1,2,4,5-Tetrahydro-1,1,4,4-tetramethyl-1,4-disiladicyclobuta- [a,d]benzene. The First Silacyclobutene Diannelated [a,d]Benzene

Author:

Gusel'nikov L. E.,Volkova V. V.,Buravtseva E. N.,Redchin A. S.,Auner N.,Herrschaft B.,Solouki B.,Tsantes G.,Ovchinnikov Y. E.,Pogozhikh S. A.,Dolgushin F. M.,Negrebetsky V. V.1

Affiliation:

1. Russian State Medical University, 1 Ostrovityanova Str., Moscow 117869, Russia

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference62 articles.

1. Intramolecular rearrangements of silenes II . Synthesis of 1-methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl-1-silacyclobutane via [4 → 2 + 2]thermocyclodecomposition — transient silene rearrangement sequence. Novel 1,4-hydrogen shift from aryl carbon to sp2 silicon of the silicon-carbon double bond

2. (b) Gusel'nikov, L. E.; Buravtsev, N. N.; Volkova, V. V.; Zubarev, Yu. E.; Buravtseva, E. N.; Pestunovich, V. A.; Lazareva, N. F. 30th Organosilicon Symposium, May 30−31, 1997, London, Western Ontario, Canada; Abstracts, p A-24.

3. Recent reviews on silenes and related compounds:  (a) Raabe, G.; Michl, J. InThe Chemistry of Organic Silicon Compounds; Rappoport, Z., Patai, S., Eds.; Wiley:  New York, 1989; Vol. 1, p 1015. (b) Gusel'nikov, L. E.; Avakyan, V. G.Sov. Sci. Rev., B:  Chem.1989,13, 39. (c) Brook, A. G.; Brook, M. A.Adv. Organomet. Chem.1995,39, 125. (d) Müller, T.; Ziche, W.; Auner, N. InThe Chemistry of Organic Silicon Compounds; Rappoport, Z., Patai, S., Eds.; Wiley:  New York, 1998; Vol. 2, p 857.

4. (a) Gusel'nikov, L. E.; Nametkin, N. S. InAdvances in OrganosiliconChemistry; Voronkov, M. G., Ed.; Mir Publishers:  Moscow, 1985; p 69.

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