Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {NpII[C5H3(SiMe3)2]3}1

Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {NpII[C5H3(SiMe3)2]3}1–

Published:2018-06-05 Issue:24 Volume:140 Page:7425-7428
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Su Jing^ORCID,Windorff Cory J.¹,Batista Enrique R.^ORCID,Evans William J.¹^ORCID,Gaunt Andrew J.^ORCID,Janicke Michael T.,Kozimor Stosh A.,Scott Brian L.²,Woen David H.¹^ORCID,Yang Ping^ORCID

Affiliation:

1. Department of Chemistry, University of California−Irvine, Irvine, California 92697-2025, United States

2. Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States

Funder

Oak Ridge Institute for Science and Education

Basic Energy Sciences

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.8b03907

Reference19 articles.

1. Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States

2. Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State

3. Small-Scale Metal-Based Syntheses of Lanthanide Iodide, Amide, and Cyclopentadienyl Complexes as Analogues for Transuranic Reactions

4. Trimethylsilyl versus Bis(trimethylsilyl) Substitution in Tris(cyclopentadienyl) Complexes of La, Ce, and Pr: Comparison of Structure, Magnetic Properties, and Reactivity

5. Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C5H4SiMe3)3U]

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