A Reactive Manganese(IV)–Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds
Author:
Affiliation:
1. Department of Chemistry, The Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, United States
Funder
Johns Hopkins University
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.8b00350
Reference93 articles.
1. Laser Flash Photolysis Generation and Kinetic Studies of Porphyrin−Manganese−Oxo Intermediates. Rate Constants for Oxidations Effected by Porphyrin−MnV−Oxo Species and Apparent Disproportionation Equilibrium Constants for Porphyrin−MnIV−Oxo Species
2. Mechanistic Insights into Hydride-Transfer and Electron-Transfer Reactions by a Manganese(IV)−Oxo Porphyrin Complex
3. Oxygen Atom Transfer Reactions from Isolated (Oxo)manganese(V) Corroles to Sulfides
4. Kinetics and Mechanism of Oxidation Reactions of Porphyrin−Iron(IV)−Oxo Intermediates
5. Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes
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