Selection between Diastereomeric Kinetic vs Thermodynamic Carbonyl Binding Modes Enables Enantioselective Iridium-Catalyzed anti-(α-Aryl)allylation of Aqueous Fluoral Hydrate and Difluoroacetaldehyde Ethyl Hemiacetal-Reference-Cited by-同舟云学术

Selection between Diastereomeric Kinetic vs Thermodynamic Carbonyl Binding Modes Enables Enantioselective Iridium-Catalyzed anti-(α-Aryl)allylation of Aqueous Fluoral Hydrate and Difluoroacetaldehyde Ethyl Hemiacetal

Published:2018-07-18 Issue:30 Volume:140 Page:9392-9395
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Cabrera James M.¹,Tauber Johannes¹,Zhang Wandi¹,Xiang Ming¹,Krische Michael J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Texas at Austin, Austin, Texas 78712, United States

Funder

Welch Foundation

Deutsche Forschungsgemeinschaft

National Institute of General Medical Sciences

Center for Green Chemistry and Catalysis, University of Texas at Austin

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.8b05725

Reference56 articles.

1. Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier

2. Catalytic nucleophilic ‘umpoled’ π-allyl reagents

3. Hydroxymethylation beyond Carbonylation: Enantioselective Iridium-Catalyzed Reductive Coupling of Formaldehyde with Allylic Acetates via Enantiotopic π-Facial Discrimination

4. Enantioselective Allylation of Carbonyl Compounds with Titanium-Carbohydrate Complexes

5. Enantioselective syntheses with titanium carbohydrate complexes. Part 7. Enantioselective allyltitanation of aldehydes with cyclopentadienyldialkoxyallyltitanium complexes

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