A Highly-Reduced Cobalt Terminal Carbyne: Divergent Metal- and α-Carbon-Centered Reactivity
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, California 92093-0358, United States
Funder
Division of Chemistry
Division of Graduate Education
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.8b05019
Reference42 articles.
1. Silylation of Iron-Bound Carbon Monoxide Affords a Terminal Fe Carbyne
2. Cobalt Fluorocarbene Complexes
3. Cobalt Fluorocarbenes: Cycloaddition Reactions with Tetrafluoroethylene and Reactivity of the Perfluorometallacyclic Products
4. Stoichiometric C═O Bond Oxidative Addition of Benzophenone by a Discrete Radical Intermediate To Form a Cobalt(I) Carbene
5. A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation
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