Steric Congestion at, and Proximity to, a Ferrous Center Leads to Hydration of α-Nitrile Substituents Forming Coordinated Carboxamides

Author:

Thallaj Nasser K.12,Orain Pierre-Yves3,Thibon Aurore14,Sandroni Martina3,Welter Richard5,Mandon Dominique13

Affiliation:

1. Laboratoire de Chimie Biomimétique des Métaux de Transition, Institut de Chimie de Strasbourg−UMR 7177, CNRS−Université de Strasbourg, Bâtiment Le Bel, 4 rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France

2. Faculty of Applied Sciences, Department of Chemistry, Kalamoon University at Deratiah, P.O. Box 222, Deratiah, Syria

3. Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, UMR 6521, CNRS−Université de Bretagne Occidentale, 6 Avenue Victor Le Gorgeu, CS 93837, F-29238 Brest Cedex 3, France

4. Laboratoire CLAC, Institut de Chimie de Strasbourg−UMR 7177, CNRS−Université de Strasbourg, 1 rue Blaise Pascal, F-67000 Strasbourg Cedex, France

5. Institut de Biologie Moléculaire des Plantes, UPR CNRS 2357, Université de Strasbourg, F-67084 Strasbourg, France

Funder

Agence Nationale de la Recherche

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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