Tautomerization of Pyridine and 2-Substituted Pyridines to Pyridylidene Ligands by the Iridium(I)–Diene Complex TpMe2Ir(η4-CH2═C(Me)C(Me)═CH2)-Reference-Cited by-同舟云学术

Tautomerization of Pyridine and 2-Substituted Pyridines to Pyridylidene Ligands by the Iridium(I)–Diene Complex TpMe2Ir(η4-CH2═C(Me)C(Me)═CH2)

Published:2014-01-02 Issue:2 Volume:33 Page:498-510
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Vattier Florencia¹,Salazar Verónica²,Paneque Margarita¹,Poveda Manuel L.¹,Álvarez Eleuterio¹

Affiliation:

1. Instituto de Investigaciones Quı́micas (IIQ) and Departamento de Quı́mica Inorgánica, Consejo Superior de Investigaciones Científicas (CSIC) and Universidad de Sevilla, Av. Américo Vespucio, 49, Isla de la Cartuja, 41092 Sevilla, Spain

2. Centro de Investigaciones Quı́micas, Universidad Autónoma del Estado de Hidalgo, Carretera Pachuca a Tulancingo Km 4.5, 42184 Mineral de la Reforma, Hidalgo, Mexico

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om400968s

Reference47 articles.

1. Tautomerisation of 2-Substituted Pyridines to N-Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety

2. Reactivity Studies of Iridium Pyridylidenes [TpMe2Ir(C6H5)2(C(CH)3C(R)NH] (R=H, Me, Ph)

3. Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

4. The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers

5. Pentaammineosmium(II) .eta.2-2,6-lutidine: an intermediate for carbon-hydrogen activation

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