A New Directing Mode for Singlet Oxygen Ene Reactions: The Vinylogous Gem Effect Enables a 1O2 Domino Ene/[4 + 2] Process
Author:
Affiliation:
1. Department of Chemistry, University of Cologne, 50939 Köln, Germany
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol4009602
Reference30 articles.
1. Christopher Foote's Discovery of the Role of Singlet Oxygen [1O2 (1Δg)] in Photosensitized Oxidation Reactions
2. Regioselectivity in the Ene Reaction of Singlet Oxygen with Alkenes
3. The ene reaction of singlet oxygen: kinetic and product evidence in support of a perepoxide intermediate
4. Unraveling the Mechanism of the Singlet Oxygen Ene Reaction: Recent Computational and Experimental Approaches
5. Photooxygenation of allylic alcohols: kinetic comparison of unfunctionalized alkenes with prenol-type allylic alcohols, ethers and acetates
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